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Freshly baked cakes turning bitter can be attributed to a few potential factors:

  1. Overbaking: If a cake is baked for too long or at too high a temperature, it can become overcooked, leading to a bitter taste. Overbaking causes the sugars in the cake to caramelize excessively, resulting in a burnt or bitter flavor.

  2. Excessive Baking Soda or Baking Powder: Using too much baking soda or baking powder in a cake recipe can cause the cake to rise too rapidly and then collapse, leading to a bitter taste. Additionally, an excess of these leavening agents can leave a chemical aftertaste in the cake.

  3. Rancid Ingredients: Using ingredients that have gone rancid or spoiled can introduce unpleasant flavors into the cake, including bitterness.

  4. Poor Quality Ingredients: The quality of ingredients used in baking can significantly impact the taste of the final product. If you use low-quality or expired ingredients, they may contribute to a bitter taste in the cake.

  5. Baking Powder with Aluminum: Some baking powders contain aluminum-based acid salts, which can leave a metallic and bitter taste if used in excessive amounts.

  6. Lack of Sweetness: Cakes are generally expected to have a certain level of sweetness. If a cake lacks adequate sugar or contains too much unsweetened cocoa or other bitter ingredients, it may taste bitter.

  7. Overmixing: Overmixing the batter can lead to excessive gluten development, resulting in a tough and bitter cake.

To prevent cakes from turning bitter, follow these tips:

  • Follow the recipe accurately and measure ingredients carefully.
  • Check your oven temperature and baking time to avoid overbaking.
  • Use fresh, high-quality ingredients.
  • Avoid using excessive baking soda or baking powder.
  • Consider using natural cocoa powder instead of Dutch-processed cocoa, as the latter can have a milder taste.
  • Mix the batter gently and only until the ingredients are combined to avoid overmixing.

If you've experienced bitterness in your cakes, take note of any potential issues during the baking process and adjust accordingly for your next bake.

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